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Chromium complexes, metalation Chrysanthemic acid 64 176 Cyclobutylmethyl carbanions 325 carbocations 320 radicals 8, 325 Cine- vs ipso-substitution Cinnamyl derivatives 294 alkylation with 93, 150, 234, 235, 245, 284 metalation 150, 171, 202 reduction 95 Cyclohexane, autoxidation 46 Cyclohexanes, conformation 20 Cyclohexanones 149, 311 Cyclohexene, epoxidation 39 Cyclohexylmethyl carbocation Cyclometalation, Pd-complexes 298 Cyclooctene, epoxidation 39 Cyclopalladation 281, 298 Cyclopentadiene formation 36 pKa 161 Cyclopentadienyl cation 196 Cyclopentanones 311 Cyclopentylmethyl carbocation 320 Cyclopentenediones 196 Cyclopropane, pKa 161 Cyclopropanes preparation 157, 158, 167, 168, 170, 192, 252, 320324 pyrolysis 36 ring opening 36, 51, 320, 322, 325 Cyclopropenes 172, 197 Cyclopropyl ketones 324 Cyclopropyl sulfonates, Sn2 Cyclopropylidenes 39 Cyclopropylmethyl carbanions 322 carbocations 314 radicals 322, 323 Cycloreversion 36, 37 Cysteine, O-alkylation 252 d D (bond dissociation enthalpy) 46 Darkening of arenes 49 DAST 230 DBU, N-alkylation 250 Dealkylation of amines 66, 200 pyridines 39 Cistrans isomerization Clustering 44 Combustion 52 Configuration, effect on stability Configurational stability of enolates 197, 198 Grignard reagents 200202 organocopper compounds organolithium compounds organomercury compounds organozinc compounds Conformation amides and esters 315 effects of hyperconjugation on Conjugation 42, 75 Contraction of rings Convergent synthesis Cope rearrangement Coupling constants Cross-coupling 282301 Crotonic acid derivatives Crowded molecules 35, 77, 233, 239, 242, 261272, 296 Cumulenes, see Allenes Cuprates, see Organocopper compounds Curcumine 48 CurtinHammett principle 13 Cyanide, reaction with epoxides Cyanides, see Nitriles Cyanoacetic acid esters, C-alkylation Cyanohydrins, O-acylation Cyclic substrates, Sn2 at Cyclization 309328 Baldwins rules 309 272 74, 75 of carbanions 190193 Cycloalkanes, heats of combustion Cycloalkenes, epoxidation 39 Cycloalkylmethyl carbocations Cyclobutanes formation 43, 315, 320, 325 fragmentation 8, 36, 37, 39 ring expansion 320 319 Cyclobutanols, fragmentation Cyclobutenediones, as starting material Cyclobutenes, formation 185, 326 Cyclobutenone 197 68, 95, 287291 51 109 2 5 23 199, 201, 202 189, 190 320 153, 154 74, 75 202, 203 online forex TJK 198 202, 203 19 119 320 Dearomatization Decalins 5 Decarboxylation Deflagration 52 Dehalogenation Dehydrogenation Design of a synthesis 2 Detonations 52 Diacids 334 36 148 7 163 159, 266 Index 361 15.
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